The Workman’s History of Calcium Chloride Testing (F1869)
Moisture Vapor Emissions
The Calcium Chloride moisture test produced data based on moisture vapor emission rate (MVER), the quantitative indication of how many pounds of slab moisture evaporated from 1000 square feet of concrete over a 24-hour period. The applicable industry standard for this test, ASTM F1869, defined the scope of Calcium Chloride testing: “This test method covers the quantitative determination of the rate of moisture vapor emitted from below-grade, on-grade, and above-grade (suspended) bare concrete floors.”
Although F1869 states that Calcium Chloride does not address all concrete safety concerns, manufacturers and installers declared (with warranty) that an industry-standard MVER of three pounds satisfied ASTM F 1869. At that point, it was safe to install floor covering over a concrete substrate.
Concrete moisture vapor migrates from the bottom of concrete slabs to their surfaces in order to evaporate. This is how concrete dries. Once poured, all concrete slabs require time for concrete moisture to reach equilibrium with the relative humidity (RH) of the slab’s surroundings. Generally, high ambient RH slows concrete drying as the slab absorbs moisture vapor; low ambient RH causes concrete to emit moisture vapor. Therefore, the natural migration process of concrete moisture drying is influenced by environment.
Where the challenge became clear was in determining whether the surface emission rate determined by desiccant weight gain truly reflected the moisture conditions deeper in the slab.
If quantitative assessment indicates moisture vapor emissions, building trades experienced decades of qualitative difficulties with the Calcium Chloride moisture test. In fact, moisture-plagued concrete slabs certified by ASTM F1869 protocol proved to be a patterned and persistent challenge to the concrete flooring industry – so much so that industry professionals began to investigate the scientific integrity of the Calcium Chloride moisture test.
Problem 1: surface measurement. Calcium Chloride measured only the top one-half to three-quarters-inch of the slab.
Problem 2: distorted readings. Calcium Chloride tended to underestimate the true moisture conditions at the high end of the moisture spectrum, while it tended to overestimate the moisture conditions of older slabs. Builders, then, made threshold floor covering decisions based on errant readings.
Problem 3: scope of assessment. Calcium Chloride failed to methodologically account for the fact that concentrated concrete moisture resides at greater depth than ever measured by the test. This led to continued moisture problems when that moisture eventually reached a covered concrete surface where they could no longer evaporate.
In light of such research, the American Society for Testing and Materials made two changes to moisture measurement industry standards. First, it amended ASTM F 1869 to remove the Calcium Chloride moisture test as a means of measuring lightweight concrete moisture. Second, ASTM created F2170, a new standard that recognized in-situ relative humidity testing as an integral assessment method.
The Calcium Chloride moisture test is a building practice with lineage. It remains rooted in ASTM standard F1869 as the source of many tests tried. But their truth has entered a new era and the challenges of moisture emissions-based testing are becoming increasingly clear.